Hi Anirvan,
you need to upload a program jar-file before you can execute it (via the "Select a program to upload" field). No program is available without uploading it first.
After uploading, the program will appear in the column on the left-hand side.
Check the box next to it to select it and give program parameters in the arguments box (bottom left).
Then hit the "Run Job" button next to it.
Best, Fabian